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The Vibrational Frequency is the frequency of photons on the excited state. Check FAQs
vvib=v0->33(1-(4xe))
vvib - Vibrational Frequency?v0->3 - Second Overtone Frequency?xe - Anharmonicity Constant?

Vibrational Frequency given Second Overtone Frequency Example

With values
With units
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Here is how the Vibrational Frequency given Second Overtone Frequency equation looks like with Values.

Here is how the Vibrational Frequency given Second Overtone Frequency equation looks like with Units.

Here is how the Vibrational Frequency given Second Overtone Frequency equation looks like.

0.0067Edit=0.5Edit3(1-(40.24Edit))
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Vibrational Frequency given Second Overtone Frequency Solution

Follow our step by step solution on how to calculate Vibrational Frequency given Second Overtone Frequency?

FIRST Step Consider the formula
vvib=v0->33(1-(4xe))
Next Step Substitute values of Variables
vvib=0.5Hz3(1-(40.24))
Next Step Prepare to Evaluate
vvib=0.53(1-(40.24))
Next Step Evaluate
vvib=0.00666666666666667Hz
LAST Step Rounding Answer
vvib=0.0067Hz

Vibrational Frequency given Second Overtone Frequency Formula Elements

Variables
Vibrational Frequency
The Vibrational Frequency is the frequency of photons on the excited state.
Symbol: vvib
Measurement: FrequencyUnit: Hz
Note: Value can be positive or negative.
Second Overtone Frequency
Second Overtone Frequency is the frequency of photons on the second excited state/ overtone band of a diatomic molecule.
Symbol: v0->3
Measurement: FrequencyUnit: Hz
Note: Value can be positive or negative.
Anharmonicity Constant
Anharmonicity Constant is the deviation of a system from being a harmonic oscillator which is related to the vibrational energy levels of diatomic molecule.
Symbol: xe
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.

Other Formulas to find Vibrational Frequency

​Go Vibrational Frequency given Fundamental Frequency
vvib=v0->11-2xe
​Go Vibrational Frequency given First Overtone Frequency
vvib=v0->22(1-3xe)

Other formulas in Vibrational Spectroscopy category

​Go Vibrational Quantum Number using Vibrational Frequency
v=(Evf[hP]vvib)-12
​Go Vibrational Quantum Number using Vibrational Wavenumber
v=(Evf[hP]ω')-12
​Go Rotational Constant for Vibrational State
Bv=Be+(αe(v+12))
​Go Rotational Constant Related to Equilibrium
Be=Bv-(αe(v+12))

How to Evaluate Vibrational Frequency given Second Overtone Frequency?

Vibrational Frequency given Second Overtone Frequency evaluator uses Vibrational Frequency = Second Overtone Frequency/3*(1-(4*Anharmonicity Constant)) to evaluate the Vibrational Frequency, The Vibrational frequency given second overtone frequency formula is defined as the frequency of photons on the excited state of a diatomic molecule. Vibrational Frequency is denoted by vvib symbol.

How to evaluate Vibrational Frequency given Second Overtone Frequency using this online evaluator? To use this online evaluator for Vibrational Frequency given Second Overtone Frequency, enter Second Overtone Frequency (v0->3) & Anharmonicity Constant (xe) and hit the calculate button.

FAQs on Vibrational Frequency given Second Overtone Frequency

What is the formula to find Vibrational Frequency given Second Overtone Frequency?
The formula of Vibrational Frequency given Second Overtone Frequency is expressed as Vibrational Frequency = Second Overtone Frequency/3*(1-(4*Anharmonicity Constant)). Here is an example- 0.006667 = 0.5/3*(1-(4*0.24)).
How to calculate Vibrational Frequency given Second Overtone Frequency?
With Second Overtone Frequency (v0->3) & Anharmonicity Constant (xe) we can find Vibrational Frequency given Second Overtone Frequency using the formula - Vibrational Frequency = Second Overtone Frequency/3*(1-(4*Anharmonicity Constant)).
What are the other ways to Calculate Vibrational Frequency?
Here are the different ways to Calculate Vibrational Frequency-
  • Vibrational Frequency=Fundamental Frequency/(1-2*Anharmonicity Constant)OpenImg
  • Vibrational Frequency=First Overtone Frequency/2*(1-3*Anharmonicity Constant)OpenImg
Can the Vibrational Frequency given Second Overtone Frequency be negative?
Yes, the Vibrational Frequency given Second Overtone Frequency, measured in Frequency can be negative.
Which unit is used to measure Vibrational Frequency given Second Overtone Frequency?
Vibrational Frequency given Second Overtone Frequency is usually measured using the Hertz[Hz] for Frequency. Petahertz[Hz], Terahertz[Hz], Gigahertz[Hz] are the few other units in which Vibrational Frequency given Second Overtone Frequency can be measured.
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