Stern Volmner Constant Formula

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Stern Volmner Constant is the bimolecular rate constant of the fluorescence quenching process due to a short-range interaction of species. Check FAQs
KSV=(I_oIF)-1[Q]
KSV - Stern Volmner Constant?I_o - Intensity Without Quenching?IF - Fluorosence Intensity?[Q] - Quencher Concentration given Degree of Exciplex?

Stern Volmner Constant Example

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With units
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Here is how the Stern Volmner Constant equation looks like with Values.

Here is how the Stern Volmner Constant equation looks like with Units.

Here is how the Stern Volmner Constant equation looks like.

-0.0056Edit=(238Edit240Edit)-11.5Edit
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Stern Volmner Constant Solution

Follow our step by step solution on how to calculate Stern Volmner Constant?

FIRST Step Consider the formula
KSV=(I_oIF)-1[Q]
Next Step Substitute values of Variables
KSV=(238W/m²240W/m²)-11.5
Next Step Prepare to Evaluate
KSV=(238240)-11.5
Next Step Evaluate
KSV=-0.00555555555555554
LAST Step Rounding Answer
KSV=-0.0056

Stern Volmner Constant Formula Elements

Variables
Stern Volmner Constant
Stern Volmner Constant is the bimolecular rate constant of the fluorescence quenching process due to a short-range interaction of species.
Symbol: KSV
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Intensity Without Quenching
Intensity Without Quenching is the power transferred per unit area, where the area is measured on the plane perpendicular to the direction of propagation of the energy.
Symbol: I_o
Measurement: IntensityUnit: W/m²
Note: Value can be positive or negative.
Fluorosence Intensity
Fluorosence Intensity formula is defined as the power transferred per unit area, where the area is measured on the plane perpendicular to the direction of propagation of the energy.
Symbol: IF
Measurement: IntensityUnit: W/m²
Note: Value can be positive or negative.
Quencher Concentration given Degree of Exciplex
Quencher Concentration given Degree of Exciplex is the concentration of substance that decreases fluoroscence intensity.
Symbol: [Q]
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.

Other formulas in Emission Spectroscopy category

​Go Collisional Energy Transfer
Rcollision =Kq[Q][MS1]
​Go Degree of Exciplex Formation
α=Keq[Q]1+(Keq[Q])
​Go Difference in Acidity between Ground and Excited State
Δpka=pKaExcited-pKaground
​Go Equilibrium Constant for Exciplex Formation
Keq=11-α-1

How to Evaluate Stern Volmner Constant?

Stern Volmner Constant evaluator uses Stern Volmner Constant = ((Intensity Without Quenching/Fluorosence Intensity)-1)/Quencher Concentration given Degree of Exciplex to evaluate the Stern Volmner Constant, The Stern Volmner Constant formula is defined as the bimolecular rate constant of the fluorescence quenching process due to a short-range interaction of species. If the fluorescence quantum yield remains proportional to the integrated emission intensity upon addition of the quencher. Stern Volmner Constant is denoted by KSV symbol.

How to evaluate Stern Volmner Constant using this online evaluator? To use this online evaluator for Stern Volmner Constant, enter Intensity Without Quenching (I_o), Fluorosence Intensity (IF) & Quencher Concentration given Degree of Exciplex ([Q]) and hit the calculate button.

FAQs on Stern Volmner Constant

What is the formula to find Stern Volmner Constant?
The formula of Stern Volmner Constant is expressed as Stern Volmner Constant = ((Intensity Without Quenching/Fluorosence Intensity)-1)/Quencher Concentration given Degree of Exciplex. Here is an example- -0.005556 = ((238/240)-1)/1.5.
How to calculate Stern Volmner Constant?
With Intensity Without Quenching (I_o), Fluorosence Intensity (IF) & Quencher Concentration given Degree of Exciplex ([Q]) we can find Stern Volmner Constant using the formula - Stern Volmner Constant = ((Intensity Without Quenching/Fluorosence Intensity)-1)/Quencher Concentration given Degree of Exciplex.
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