Specific Rotation of Optically Active Compound Formula

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The Specific Rotation of a compound is an intensive property that is used to quantify the enantiomeric excess of that compound. Check FAQs
[α]D=αlc
[α]D - Specific Rotation?α - Observed Rotation?l - Length Of Sample Tube?c - Concentration of Solution in Polarimeter?

Specific Rotation of Optically Active Compound Example

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With units
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Here is how the Specific Rotation of Optically Active Compound equation looks like with Values.

Here is how the Specific Rotation of Optically Active Compound equation looks like with Units.

Here is how the Specific Rotation of Optically Active Compound equation looks like.

11.25Edit=45Edit2Edit2Edit
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Specific Rotation of Optically Active Compound Solution

Follow our step by step solution on how to calculate Specific Rotation of Optically Active Compound?

FIRST Step Consider the formula
[α]D=αlc
Next Step Substitute values of Variables
[α]D=45°2dm2g/mL
Next Step Convert Units
[α]D=0.7854rad0.2m2000kg/m³
Next Step Prepare to Evaluate
[α]D=0.78540.22000
Next Step Evaluate
[α]D=0.00196349540849325rad.m³.kg⁻¹.m⁻¹
LAST Step Convert to Output's Unit
[α]D=11.25deg.mL.g⁻¹.dm⁻¹

Specific Rotation of Optically Active Compound Formula Elements

Variables
Specific Rotation
The Specific Rotation of a compound is an intensive property that is used to quantify the enantiomeric excess of that compound.
Symbol: [α]D
Measurement: Specific RotationUnit: deg.mL.g⁻¹.dm⁻¹
Note: Value can be positive or negative.
Observed Rotation
Observed rotation is the extent to which plane-polarized light is rotated by a solution of an optically active compound.
Symbol: α
Measurement: AngleUnit: °
Note: Value can be positive or negative.
Length Of Sample Tube
Length Of Sample Tube is the measurement or extent of the tube from end to end in the polarimeter.
Symbol: l
Measurement: LengthUnit: dm
Note: Value can be positive or negative.
Concentration of Solution in Polarimeter
Concentration of Solution in Polarimeter is the abundance of a constituent divided by the total volume of a mixture.
Symbol: c
Measurement: Mass ConcentrationUnit: g/mL
Note: Value can be positive or negative.

Other formulas in Optical Activity category

​Go Optical Purity
OP=([α]obs[α]max)100
​Go Enantiomeric Excess
ee=|FR-FS|
​Go Percent Enantiomeric Excess
%ee=|FR-FS|100
​Go Fraction of Major Isomer
FR=50+(%ee2)

How to Evaluate Specific Rotation of Optically Active Compound?

Specific Rotation of Optically Active Compound evaluator uses Specific Rotation = Observed Rotation/(Length Of Sample Tube*Concentration of Solution in Polarimeter) to evaluate the Specific Rotation, The Specific Rotation of Optically Active Compound formula is defined as the change in orientation of monochromatic plane-polarized light, per unit distance–concentration product, as the light passes through a sample of a compound in solution. Specific Rotation is denoted by [α]D symbol.

How to evaluate Specific Rotation of Optically Active Compound using this online evaluator? To use this online evaluator for Specific Rotation of Optically Active Compound, enter Observed Rotation (α), Length Of Sample Tube (l) & Concentration of Solution in Polarimeter (c) and hit the calculate button.

FAQs on Specific Rotation of Optically Active Compound

What is the formula to find Specific Rotation of Optically Active Compound?
The formula of Specific Rotation of Optically Active Compound is expressed as Specific Rotation = Observed Rotation/(Length Of Sample Tube*Concentration of Solution in Polarimeter). Here is an example- 64457.75 = 0.785398163397301/(0.2*2000).
How to calculate Specific Rotation of Optically Active Compound?
With Observed Rotation (α), Length Of Sample Tube (l) & Concentration of Solution in Polarimeter (c) we can find Specific Rotation of Optically Active Compound using the formula - Specific Rotation = Observed Rotation/(Length Of Sample Tube*Concentration of Solution in Polarimeter).
Can the Specific Rotation of Optically Active Compound be negative?
Yes, the Specific Rotation of Optically Active Compound, measured in Specific Rotation can be negative.
Which unit is used to measure Specific Rotation of Optically Active Compound?
Specific Rotation of Optically Active Compound is usually measured using the Degree Milliliter per Gram per Decimeter[deg.mL.g⁻¹.dm⁻¹] for Specific Rotation. Radian Cubic Meter per Kilogram per Meter[deg.mL.g⁻¹.dm⁻¹] are the few other units in which Specific Rotation of Optically Active Compound can be measured.
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