Singlet State Concentration Formula

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Concentration of Singlet State is the number of molecules present in the singlet excited state. Check FAQs
[MSs1]=IaKf+KNR+KISC+KIC
[MSs1] - Concentration of Singlet State?Ia - Absorption Intensity?Kf - Rate Constant of Fluoroscence?KNR - Rate Constant of Non Radiative Reaction?KISC - Rate Constant of Intersystem Crossing?KIC - Rate Constant of Internal Conversion?

Singlet State Concentration Example

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With units
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Here is how the Singlet State Concentration equation looks like with Values.

Here is how the Singlet State Concentration equation looks like with Units.

Here is how the Singlet State Concentration equation looks like.

3.9E-6Edit=250Edit750Edit+35Edit+64000Edit+45.5Edit
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Singlet State Concentration Solution

Follow our step by step solution on how to calculate Singlet State Concentration?

FIRST Step Consider the formula
[MSs1]=IaKf+KNR+KISC+KIC
Next Step Substitute values of Variables
[MSs1]=250W/m²750rev/s+35rev/s+64000rev/s+45.5rev/s
Next Step Convert Units
[MSs1]=250W/m²750Hz+35Hz+64000Hz+45.5Hz
Next Step Prepare to Evaluate
[MSs1]=250750+35+64000+45.5
Next Step Evaluate
[MSs1]=0.00385620965440649mol/m³
Next Step Convert to Output's Unit
[MSs1]=3.85620965440649E-06mol/L
LAST Step Rounding Answer
[MSs1]=3.9E-6mol/L

Singlet State Concentration Formula Elements

Variables
Concentration of Singlet State
Concentration of Singlet State is the number of molecules present in the singlet excited state.
Symbol: [MSs1]
Measurement: Molar ConcentrationUnit: mol/L
Note: Value can be positive or negative.
Absorption Intensity
Absorption Intensity obtained by integrating the area under the absorption line—is proportional to the amount of the absorbing substance present.
Symbol: Ia
Measurement: IntensityUnit: W/m²
Note: Value can be positive or negative.
Rate Constant of Fluoroscence
Rate Constant of Fluoroscence is the rate at which spontaneous emission occurs.
Symbol: Kf
Measurement: FrequencyUnit: rev/s
Note: Value can be positive or negative.
Rate Constant of Non Radiative Reaction
Rate Constant of Non Radiative Reaction is defined as the rate at which deactivation occurs in the form of heat energy.
Symbol: KNR
Measurement: FrequencyUnit: rev/s
Note: Value can be positive or negative.
Rate Constant of Intersystem Crossing
Rate Constant of Intersystem Crossing is the rate of decay from excited singlet electronic state to triplet state.
Symbol: KISC
Measurement: FrequencyUnit: rev/s
Note: Value can be positive or negative.
Rate Constant of Internal Conversion
Rate Constant of Internal Conversion is the rate of decay from excited singlet electronic state to triplet state.
Symbol: KIC
Measurement: FrequencyUnit: rev/s
Note: Value can be positive or negative.

Other formulas in Emission Spectroscopy category

​Go Fluorescence Rate Constant
Kf=Rf[MS1]
​Go Fluoroscence Intensity
IF=KfIaKf+KNR
​Go Fluoroscence Intensity without Quenching
I_o=KfIaKNR+Kf
​Go Initial Intensity given Degree of Exciplex Formation
Ioα=KfKeqKf+KNR

How to Evaluate Singlet State Concentration?

Singlet State Concentration evaluator uses Concentration of Singlet State = Absorption Intensity/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction+Rate Constant of Intersystem Crossing+Rate Constant of Internal Conversion) to evaluate the Concentration of Singlet State, The Singlet State Concentration formula is defined as is the number of molecules present in the singlet excited state. The concentration of a substance is the quantity of solute present in a given quantity of solution. Concentrations are usually expressed in terms of molarity, defined as the number of moles of solute in 1 L of solution. Concentration of Singlet State is denoted by [MSs1] symbol.

How to evaluate Singlet State Concentration using this online evaluator? To use this online evaluator for Singlet State Concentration, enter Absorption Intensity (Ia), Rate Constant of Fluoroscence (Kf), Rate Constant of Non Radiative Reaction (KNR), Rate Constant of Intersystem Crossing (KISC) & Rate Constant of Internal Conversion (KIC) and hit the calculate button.

FAQs on Singlet State Concentration

What is the formula to find Singlet State Concentration?
The formula of Singlet State Concentration is expressed as Concentration of Singlet State = Absorption Intensity/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction+Rate Constant of Intersystem Crossing+Rate Constant of Internal Conversion). Here is an example- 3.9E-9 = 250/(750+35+64000+45.5).
How to calculate Singlet State Concentration?
With Absorption Intensity (Ia), Rate Constant of Fluoroscence (Kf), Rate Constant of Non Radiative Reaction (KNR), Rate Constant of Intersystem Crossing (KISC) & Rate Constant of Internal Conversion (KIC) we can find Singlet State Concentration using the formula - Concentration of Singlet State = Absorption Intensity/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction+Rate Constant of Intersystem Crossing+Rate Constant of Internal Conversion).
Can the Singlet State Concentration be negative?
Yes, the Singlet State Concentration, measured in Molar Concentration can be negative.
Which unit is used to measure Singlet State Concentration?
Singlet State Concentration is usually measured using the Mole per Liter[mol/L] for Molar Concentration. Mole per Cubic Meter[mol/L], Mole per Cubic Millimeter[mol/L], Kilomole per Cubic Meter[mol/L] are the few other units in which Singlet State Concentration can be measured.
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