Phosphorescence Quantum Yield given Intersystem Quantum Yield Formula

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Phosphorescence Quantum Yield given ISC is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed. Check FAQs
φph_ISC=(KpIa)((Iaφ_ISCKTTA)12)
φph_ISC - Phosphorescence Quantum Yield given ISC?Kp - Phosphorescence Rate Constant?Ia - Absorption Intensity?φ_ISC - Triplet State Quantum Yield?KTTA - Rate Constant of Triplet Triplet Anhilation?

Phosphorescence Quantum Yield given Intersystem Quantum Yield Example

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Here is how the Phosphorescence Quantum Yield given Intersystem Quantum Yield equation looks like with Values.

Here is how the Phosphorescence Quantum Yield given Intersystem Quantum Yield equation looks like with Units.

Here is how the Phosphorescence Quantum Yield given Intersystem Quantum Yield equation looks like.

70.6018Edit=(45Edit250Edit)((250Edit40Edit65Edit)12)
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Phosphorescence Quantum Yield given Intersystem Quantum Yield Solution

Follow our step by step solution on how to calculate Phosphorescence Quantum Yield given Intersystem Quantum Yield?

FIRST Step Consider the formula
φph_ISC=(KpIa)((Iaφ_ISCKTTA)12)
Next Step Substitute values of Variables
φph_ISC=(45rev/s250W/m²)((250W/m²4065L/(mol*s))12)
Next Step Convert Units
φph_ISC=(45Hz250W/m²)((250W/m²400.065m³/(mol*s))12)
Next Step Prepare to Evaluate
φph_ISC=(45250)((250400.065)12)
Next Step Evaluate
φph_ISC=70.6018086497462
LAST Step Rounding Answer
φph_ISC=70.6018

Phosphorescence Quantum Yield given Intersystem Quantum Yield Formula Elements

Variables
Phosphorescence Quantum Yield given ISC
Phosphorescence Quantum Yield given ISC is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed.
Symbol: φph_ISC
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Phosphorescence Rate Constant
Phosphorescence Rate Constant is defined as the rate at which phosphorescence occurs during emission from triplet to singlet state.
Symbol: Kp
Measurement: FrequencyUnit: rev/s
Note: Value can be positive or negative.
Absorption Intensity
Absorption Intensity obtained by integrating the area under the absorption line—is proportional to the amount of the absorbing substance present.
Symbol: Ia
Measurement: IntensityUnit: W/m²
Note: Value can be positive or negative.
Triplet State Quantum Yield
Triplet State Quantum yield is the rate if triplet state intensity to absorption intensity.
Symbol: φ_ISC
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Rate Constant of Triplet Triplet Anhilation
Rate constant of Triplet Triplet Anhilation is the measure of energy transfer mechanism between two molecules in their triplet state, and is related to the Dexter energy transfer mechanism.
Symbol: KTTA
Measurement: Second Order Reaction Rate ConstantUnit: L/(mol*s)
Note: Value can be positive or negative.

Other formulas in Emission Spectroscopy category

​Go Fluorescence Quantum Yield
φfl=KradKrad+RIC+KISC+Kq
​Go Fluoroscence Quantum Yield given Phosphorescence Quantum Yield
φFL=φph(Kf[MS1]Kp[MT])
​Go Phosphorescence Quantum Yield
φp=KradKrad+KNR
​Go Phosphorescence Quantum Yield given Triplet Triplet Annhilation Constant
φph-TTA=KpφISCKp+KISC+KTTA

How to Evaluate Phosphorescence Quantum Yield given Intersystem Quantum Yield?

Phosphorescence Quantum Yield given Intersystem Quantum Yield evaluator uses Phosphorescence Quantum Yield given ISC = (Phosphorescence Rate Constant/Absorption Intensity)*(((Absorption Intensity*Triplet State Quantum Yield)/Rate Constant of Triplet Triplet Anhilation)^(1/2)) to evaluate the Phosphorescence Quantum Yield given ISC, The Phosphorescence Quantum Yield given Intersystem Quantum Yield formula is defined is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed. Phosphorescence Quantum Yield given ISC is denoted by φph_ISC symbol.

How to evaluate Phosphorescence Quantum Yield given Intersystem Quantum Yield using this online evaluator? To use this online evaluator for Phosphorescence Quantum Yield given Intersystem Quantum Yield, enter Phosphorescence Rate Constant (Kp), Absorption Intensity (Ia), Triplet State Quantum Yield _ISC) & Rate Constant of Triplet Triplet Anhilation (KTTA) and hit the calculate button.

FAQs on Phosphorescence Quantum Yield given Intersystem Quantum Yield

What is the formula to find Phosphorescence Quantum Yield given Intersystem Quantum Yield?
The formula of Phosphorescence Quantum Yield given Intersystem Quantum Yield is expressed as Phosphorescence Quantum Yield given ISC = (Phosphorescence Rate Constant/Absorption Intensity)*(((Absorption Intensity*Triplet State Quantum Yield)/Rate Constant of Triplet Triplet Anhilation)^(1/2)). Here is an example- 70.60181 = (45/250)*(((250*40)/0.065)^(1/2)).
How to calculate Phosphorescence Quantum Yield given Intersystem Quantum Yield?
With Phosphorescence Rate Constant (Kp), Absorption Intensity (Ia), Triplet State Quantum Yield _ISC) & Rate Constant of Triplet Triplet Anhilation (KTTA) we can find Phosphorescence Quantum Yield given Intersystem Quantum Yield using the formula - Phosphorescence Quantum Yield given ISC = (Phosphorescence Rate Constant/Absorption Intensity)*(((Absorption Intensity*Triplet State Quantum Yield)/Rate Constant of Triplet Triplet Anhilation)^(1/2)).
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