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The Madelung constant is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges. Check FAQs
M=(Etot-(BMr0nborn))4π[Permitivity-vacuum]r0-(q2)([Charge-e]2)
M - Madelung Constant?Etot - Total energy of Ion in an Ionic Crystal?BM - Repulsive Interaction Constant given M?r0 - Distance of Closest Approach?nborn - Born Exponent?q - Charge?[Permitivity-vacuum] - Permittivity of vacuum?[Charge-e] - Charge of electron?π - Archimedes' constant?

Madelung Constant using Total Energy of Ion Example

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Here is how the Madelung Constant using Total Energy of Ion equation looks like with Values.

Here is how the Madelung Constant using Total Energy of Ion equation looks like with Units.

Here is how the Madelung Constant using Total Energy of Ion equation looks like.

1.6954Edit=(7E-23Edit-(4.1E-29Edit60Edit0.9926Edit))43.14168.9E-1260Edit-(0.3Edit2)(1.6E-192)
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Madelung Constant using Total Energy of Ion Solution

Follow our step by step solution on how to calculate Madelung Constant using Total Energy of Ion?

FIRST Step Consider the formula
M=(Etot-(BMr0nborn))4π[Permitivity-vacuum]r0-(q2)([Charge-e]2)
Next Step Substitute values of Variables
M=(7E-23J-(4.1E-2960A0.9926))4π[Permitivity-vacuum]60A-(0.3C2)([Charge-e]2)
Next Step Substitute values of Constants
M=(7E-23J-(4.1E-2960A0.9926))43.14168.9E-12F/m60A-(0.3C2)(1.6E-19C2)
Next Step Convert Units
M=(7E-23J-(4.1E-296E-9m0.9926))43.14168.9E-12F/m6E-9m-(0.3C2)(1.6E-19C2)
Next Step Prepare to Evaluate
M=(7E-23-(4.1E-296E-90.9926))43.14168.9E-126E-9-(0.32)(1.6E-192)
Next Step Evaluate
M=1.69538733246286
LAST Step Rounding Answer
M=1.6954

Madelung Constant using Total Energy of Ion Formula Elements

Variables
Constants
Madelung Constant
The Madelung constant is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges.
Symbol: M
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Total energy of Ion in an Ionic Crystal
The Total energy of Ion in an Ionic Crystal in the lattice is the sum of Madelung Energy and Repulsive potential energy.
Symbol: Etot
Measurement: EnergyUnit: J
Note: Value can be positive or negative.
Repulsive Interaction Constant given M
The Repulsive Interaction Constant given M, (where M= Madelung Constant) is the constant scaling the strength of the repulsive interaction.
Symbol: BM
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Distance of Closest Approach
Distance of Closest Approach is the distance to which an alpha particle comes closer to the nucleus.
Symbol: r0
Measurement: LengthUnit: A
Note: Value can be positive or negative.
Born Exponent
The Born Exponent is a number between 5 and 12, determined experimentally by measuring the compressibility of the solid, or derived theoretically.
Symbol: nborn
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Charge
A Charge is the fundamental property of forms of matter that exhibit electrostatic attraction or repulsion in the presence of other matter.
Symbol: q
Measurement: Electric ChargeUnit: C
Note: Value can be positive or negative.
Permittivity of vacuum
Permittivity of vacuum is a fundamental physical constant that describes the ability of a vacuum to permit the transmission of electric field lines.
Symbol: [Permitivity-vacuum]
Value: 8.85E-12 F/m
Charge of electron
Charge of electron is a fundamental physical constant, representing the electric charge carried by an electron, which is the elementary particle with a negative electric charge.
Symbol: [Charge-e]
Value: 1.60217662E-19 C
Archimedes' constant
Archimedes' constant is a mathematical constant that represents the ratio of the circumference of a circle to its diameter.
Symbol: π
Value: 3.14159265358979323846264338327950288

Other Formulas to find Madelung Constant

​Go Madelung Constant given Repulsive Interaction Constant
M=BM4π[Permitivity-vacuum]nborn(q2)([Charge-e]2)(r0nborn-1)
​Go Madelung Constant using Born Lande Equation
M=-U4π[Permitivity-vacuum]r0(1-(1nborn))([Charge-e]2)[Avaga-no]z+z-
​Go Madelung Constant using Born-Mayer equation
M=-U4π[Permitivity-vacuum]r0[Avaga-no]z+z-([Charge-e]2)(1-(ρr0))
​Go Madelung Constant using Kapustinskii Approximation
M=0.88Nions

Other formulas in Madelung Constant category

​Go Madelung Energy
EM=-M(q2)([Charge-e]2)4π[Permitivity-vacuum]r0
​Go Madelung Energy using Total Energy of Ion
EM=Etot-E
​Go Madelung Energy using Total Energy of Ion given Distance
EM=Etot-(BMr0nborn)

How to Evaluate Madelung Constant using Total Energy of Ion?

Madelung Constant using Total Energy of Ion evaluator uses Madelung Constant = ((Total energy of Ion in an Ionic Crystal-(Repulsive Interaction Constant given M/(Distance of Closest Approach^Born Exponent)))*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/(-(Charge^2)*([Charge-e]^2)) to evaluate the Madelung Constant, The Madelung constant using Total Energy of Ion is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges. Madelung Constant is denoted by M symbol.

How to evaluate Madelung Constant using Total Energy of Ion using this online evaluator? To use this online evaluator for Madelung Constant using Total Energy of Ion, enter Total energy of Ion in an Ionic Crystal (Etot), Repulsive Interaction Constant given M (BM), Distance of Closest Approach (r0), Born Exponent (nborn) & Charge (q) and hit the calculate button.

FAQs on Madelung Constant using Total Energy of Ion

What is the formula to find Madelung Constant using Total Energy of Ion?
The formula of Madelung Constant using Total Energy of Ion is expressed as Madelung Constant = ((Total energy of Ion in an Ionic Crystal-(Repulsive Interaction Constant given M/(Distance of Closest Approach^Born Exponent)))*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/(-(Charge^2)*([Charge-e]^2)). Here is an example- 1.695387 = ((7.02E-23-(4.1E-29/(6E-09^0.9926)))*4*pi*[Permitivity-vacuum]*6E-09)/(-(0.3^2)*([Charge-e]^2)).
How to calculate Madelung Constant using Total Energy of Ion?
With Total energy of Ion in an Ionic Crystal (Etot), Repulsive Interaction Constant given M (BM), Distance of Closest Approach (r0), Born Exponent (nborn) & Charge (q) we can find Madelung Constant using Total Energy of Ion using the formula - Madelung Constant = ((Total energy of Ion in an Ionic Crystal-(Repulsive Interaction Constant given M/(Distance of Closest Approach^Born Exponent)))*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/(-(Charge^2)*([Charge-e]^2)). This formula also uses Permittivity of vacuum, Charge of electron, Archimedes' constant .
What are the other ways to Calculate Madelung Constant?
Here are the different ways to Calculate Madelung Constant-
  • Madelung Constant=(Repulsive Interaction Constant given M*4*pi*[Permitivity-vacuum]*Born Exponent)/((Charge^2)*([Charge-e]^2)*(Distance of Closest Approach^(Born Exponent-1)))OpenImg
  • Madelung Constant=(-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/((1-(1/Born Exponent))*([Charge-e]^2)*[Avaga-no]*Charge of Cation*Charge of Anion)OpenImg
  • Madelung Constant=(-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/([Avaga-no]*Charge of Cation*Charge of Anion*([Charge-e]^2)*(1-(Constant Depending on Compressibility/Distance of Closest Approach)))OpenImg
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