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The Madelung constant is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges. Check FAQs
M=-U4π[Permitivity-vacuum]r0[Avaga-no]z+z-([Charge-e]2)(1-(ρr0))
M - Madelung Constant?U - Lattice Energy?r0 - Distance of Closest Approach?z+ - Charge of Cation?z- - Charge of Anion?ρ - Constant Depending on Compressibility?[Permitivity-vacuum] - Permittivity of vacuum?[Avaga-no] - Avogadro’s number?[Charge-e] - Charge of electron?π - Archimedes' constant?

Madelung Constant using Born-Mayer equation Example

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Here is how the Madelung Constant using Born-Mayer equation equation looks like with Values.

Here is how the Madelung Constant using Born-Mayer equation equation looks like with Units.

Here is how the Madelung Constant using Born-Mayer equation equation looks like.

1.7168Edit=-3500Edit43.14168.9E-1260Edit6E+234Edit3Edit(1.6E-192)(1-(60.44Edit60Edit))
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Madelung Constant using Born-Mayer equation Solution

Follow our step by step solution on how to calculate Madelung Constant using Born-Mayer equation?

FIRST Step Consider the formula
M=-U4π[Permitivity-vacuum]r0[Avaga-no]z+z-([Charge-e]2)(1-(ρr0))
Next Step Substitute values of Variables
M=-3500J/mol4π[Permitivity-vacuum]60A[Avaga-no]4C3C([Charge-e]2)(1-(60.44A60A))
Next Step Substitute values of Constants
M=-3500J/mol43.14168.9E-12F/m60A6E+234C3C(1.6E-19C2)(1-(60.44A60A))
Next Step Convert Units
M=-3500J/mol43.14168.9E-12F/m6E-9m6E+234C3C(1.6E-19C2)(1-(6E-9m6E-9m))
Next Step Prepare to Evaluate
M=-350043.14168.9E-126E-96E+2343(1.6E-192)(1-(6E-96E-9))
Next Step Evaluate
M=1.71679355814139
LAST Step Rounding Answer
M=1.7168

Madelung Constant using Born-Mayer equation Formula Elements

Variables
Constants
Madelung Constant
The Madelung constant is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges.
Symbol: M
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Lattice Energy
The Lattice Energy of a crystalline solid is a measure of the energy released when ions are combined to make a compound.
Symbol: U
Measurement: Molar EnthalpyUnit: J/mol
Note: Value can be positive or negative.
Distance of Closest Approach
Distance of Closest Approach is the distance to which an alpha particle comes closer to the nucleus.
Symbol: r0
Measurement: LengthUnit: A
Note: Value can be positive or negative.
Charge of Cation
The Charge of Cation is the positive charge over a cation with fewer electron than the respective atom.
Symbol: z+
Measurement: Electric ChargeUnit: C
Note: Value can be positive or negative.
Charge of Anion
The Charge of Anion is the negative charge over an anion with more electron than the respective atom.
Symbol: z-
Measurement: Electric ChargeUnit: C
Note: Value can be positive or negative.
Constant Depending on Compressibility
The Constant Depending on Compressibility is a constant dependent on the compressibility of the crystal, 30 pm works well for all alkali metal halides.
Symbol: ρ
Measurement: LengthUnit: A
Note: Value can be positive or negative.
Permittivity of vacuum
Permittivity of vacuum is a fundamental physical constant that describes the ability of a vacuum to permit the transmission of electric field lines.
Symbol: [Permitivity-vacuum]
Value: 8.85E-12 F/m
Avogadro’s number
Avogadro’s number represents the number of entities (atoms, molecules, ions, etc.) in one mole of a substance.
Symbol: [Avaga-no]
Value: 6.02214076E+23
Charge of electron
Charge of electron is a fundamental physical constant, representing the electric charge carried by an electron, which is the elementary particle with a negative electric charge.
Symbol: [Charge-e]
Value: 1.60217662E-19 C
Archimedes' constant
Archimedes' constant is a mathematical constant that represents the ratio of the circumference of a circle to its diameter.
Symbol: π
Value: 3.14159265358979323846264338327950288

Other Formulas to find Madelung Constant

​Go Madelung Constant given Repulsive Interaction Constant
M=BM4π[Permitivity-vacuum]nborn(q2)([Charge-e]2)(r0nborn-1)
​Go Madelung Constant using Born Lande Equation
M=-U4π[Permitivity-vacuum]r0(1-(1nborn))([Charge-e]2)[Avaga-no]z+z-
​Go Madelung Constant using Kapustinskii Approximation
M=0.88Nions
​Go Madelung Constant using Madelung Energy
M=-(EM)4π[Permitivity-vacuum]r0(q2)([Charge-e]2)

Other formulas in Madelung Constant category

​Go Madelung Energy
EM=-M(q2)([Charge-e]2)4π[Permitivity-vacuum]r0
​Go Madelung Energy using Total Energy of Ion
EM=Etot-E
​Go Madelung Energy using Total Energy of Ion given Distance
EM=Etot-(BMr0nborn)

How to Evaluate Madelung Constant using Born-Mayer equation?

Madelung Constant using Born-Mayer equation evaluator uses Madelung Constant = (-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/([Avaga-no]*Charge of Cation*Charge of Anion*([Charge-e]^2)*(1-(Constant Depending on Compressibility/Distance of Closest Approach))) to evaluate the Madelung Constant, The Madelung constant using Born-Mayer equation is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges. Madelung Constant is denoted by M symbol.

How to evaluate Madelung Constant using Born-Mayer equation using this online evaluator? To use this online evaluator for Madelung Constant using Born-Mayer equation, enter Lattice Energy (U), Distance of Closest Approach (r0), Charge of Cation (z+), Charge of Anion (z-) & Constant Depending on Compressibility (ρ) and hit the calculate button.

FAQs on Madelung Constant using Born-Mayer equation

What is the formula to find Madelung Constant using Born-Mayer equation?
The formula of Madelung Constant using Born-Mayer equation is expressed as Madelung Constant = (-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/([Avaga-no]*Charge of Cation*Charge of Anion*([Charge-e]^2)*(1-(Constant Depending on Compressibility/Distance of Closest Approach))). Here is an example- 1.716794 = (-3500*4*pi*[Permitivity-vacuum]*6E-09)/([Avaga-no]*4*3*([Charge-e]^2)*(1-(6.044E-09/6E-09))).
How to calculate Madelung Constant using Born-Mayer equation?
With Lattice Energy (U), Distance of Closest Approach (r0), Charge of Cation (z+), Charge of Anion (z-) & Constant Depending on Compressibility (ρ) we can find Madelung Constant using Born-Mayer equation using the formula - Madelung Constant = (-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/([Avaga-no]*Charge of Cation*Charge of Anion*([Charge-e]^2)*(1-(Constant Depending on Compressibility/Distance of Closest Approach))). This formula also uses Permittivity of vacuum, Avogadro’s number, Charge of electron, Archimedes' constant .
What are the other ways to Calculate Madelung Constant?
Here are the different ways to Calculate Madelung Constant-
  • Madelung Constant=(Repulsive Interaction Constant given M*4*pi*[Permitivity-vacuum]*Born Exponent)/((Charge^2)*([Charge-e]^2)*(Distance of Closest Approach^(Born Exponent-1)))OpenImg
  • Madelung Constant=(-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/((1-(1/Born Exponent))*([Charge-e]^2)*[Avaga-no]*Charge of Cation*Charge of Anion)OpenImg
  • Madelung Constant=0.88*Number of IonsOpenImg
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