Fx Copy
LaTeX Copy
The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell. Check FAQs
EMF=t-(νν±)([R]T[Faraday])ln(a2a1)
EMF - EMF of Cell?t- - Transport Number of Anion?ν - Total number of Ions? - Valencies of Positive and Negative Ions?ν± - Number of Positive and Negative Ions?T - Temperature?a2 - Cathodic Ionic Activity?a1 - Anodic Ionic Activity?[R] - Universal gas constant?[Faraday] - Faraday constant?

EMF of Concentration Cell with Transference in Terms of Valencies Example

With values
With units
Only example

Here is how the EMF of Concentration Cell with Transference in Terms of Valencies equation looks like with Values.

Here is how the EMF of Concentration Cell with Transference in Terms of Valencies equation looks like with Units.

Here is how the EMF of Concentration Cell with Transference in Terms of Valencies equation looks like.

0.2001Edit=49Edit(110Edit2Edit58Edit)(8.314585Edit96485.3321)ln(0.36Edit0.2Edit)
You are here -
HomeIcon Home » Category Chemistry » Category Electrochemistry » Category EMF of Concentration Cell » fx EMF of Concentration Cell with Transference in Terms of Valencies

EMF of Concentration Cell with Transference in Terms of Valencies Solution

Follow our step by step solution on how to calculate EMF of Concentration Cell with Transference in Terms of Valencies?

FIRST Step Consider the formula
EMF=t-(νν±)([R]T[Faraday])ln(a2a1)
Next Step Substitute values of Variables
EMF=49(110258)([R]85K[Faraday])ln(0.36mol/kg0.2mol/kg)
Next Step Substitute values of Constants
EMF=49(110258)(8.314585K96485.3321)ln(0.36mol/kg0.2mol/kg)
Next Step Prepare to Evaluate
EMF=49(110258)(8.31458596485.3321)ln(0.360.2)
Next Step Evaluate
EMF=0.200051733799338V
LAST Step Rounding Answer
EMF=0.2001V

EMF of Concentration Cell with Transference in Terms of Valencies Formula Elements

Variables
Constants
Functions
EMF of Cell
The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell.
Symbol: EMF
Measurement: Electric PotentialUnit: V
Note: Value can be positive or negative.
Transport Number of Anion
The Transport Number of Anion is ratio of current carried by anion to total current.
Symbol: t-
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Total number of Ions
The Total number of ions is the number of ions present in the electrolytic solution.
Symbol: ν
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Valencies of Positive and Negative Ions
The Valencies of positive and negative ions is the valency of electrolytes with respect to electrodes with which ions are reversible.
Symbol:
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Number of Positive and Negative Ions
The Number of Positive and Negative Ions is the amount of cations and anions present in the electrolytic solution.
Symbol: ν±
Measurement: NAUnit: Unitless
Note: Value can be positive or negative.
Temperature
Temperature is the degree or intensity of heat present in a substance or object.
Symbol: T
Measurement: TemperatureUnit: K
Note: Value can be positive or negative.
Cathodic Ionic Activity
Cathodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in a cathodic half-cell.
Symbol: a2
Measurement: MolalityUnit: mol/kg
Note: Value can be positive or negative.
Anodic Ionic Activity
The Anodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in an anodic half cell.
Symbol: a1
Measurement: MolalityUnit: mol/kg
Note: Value can be positive or negative.
Universal gas constant
Universal gas constant is a fundamental physical constant that appears in the ideal gas law, relating the pressure, volume, and temperature of an ideal gas.
Symbol: [R]
Value: 8.31446261815324
Faraday constant
Faraday constant represents the charge of one mole of electrons and is used in electrochemistry to relate the amount of substance undergoing oxidation.
Symbol: [Faraday]
Value: 96485.33212
ln
The natural logarithm, also known as the logarithm to the base e, is the inverse function of the natural exponential function.
Syntax: ln(Number)

Other Formulas to find EMF of Cell

​Go EMF of Due Cell
EMF=Ecathode-Eanode
​Go EMF of Concentration Cell without Transference given Activities
EMF=([R]T[Faraday])(ln(a2a1))

How to Evaluate EMF of Concentration Cell with Transference in Terms of Valencies?

EMF of Concentration Cell with Transference in Terms of Valencies evaluator uses EMF of Cell = Transport Number of Anion*(Total number of Ions/(Valencies of Positive and Negative Ions*Number of Positive and Negative Ions))*(([R]*Temperature)/[Faraday])*ln(Cathodic Ionic Activity/Anodic Ionic Activity) to evaluate the EMF of Cell, The EMF of concentration cell with transference in terms of valencies formula is defined as the relation with the ionic activity of electrolyte of the cathodic and anodic half cell at a particular temperature. EMF of Cell is denoted by EMF symbol.

How to evaluate EMF of Concentration Cell with Transference in Terms of Valencies using this online evaluator? To use this online evaluator for EMF of Concentration Cell with Transference in Terms of Valencies, enter Transport Number of Anion (t-), Total number of Ions (ν), Valencies of Positive and Negative Ions (Z±), Number of Positive and Negative Ions (ν±), Temperature (T), Cathodic Ionic Activity (a2) & Anodic Ionic Activity (a1) and hit the calculate button.

FAQs on EMF of Concentration Cell with Transference in Terms of Valencies

What is the formula to find EMF of Concentration Cell with Transference in Terms of Valencies?
The formula of EMF of Concentration Cell with Transference in Terms of Valencies is expressed as EMF of Cell = Transport Number of Anion*(Total number of Ions/(Valencies of Positive and Negative Ions*Number of Positive and Negative Ions))*(([R]*Temperature)/[Faraday])*ln(Cathodic Ionic Activity/Anodic Ionic Activity). Here is an example- 0.200052 = 49*(110/(2*58))*(([R]*85)/[Faraday])*ln(0.36/0.2).
How to calculate EMF of Concentration Cell with Transference in Terms of Valencies?
With Transport Number of Anion (t-), Total number of Ions (ν), Valencies of Positive and Negative Ions (Z±), Number of Positive and Negative Ions (ν±), Temperature (T), Cathodic Ionic Activity (a2) & Anodic Ionic Activity (a1) we can find EMF of Concentration Cell with Transference in Terms of Valencies using the formula - EMF of Cell = Transport Number of Anion*(Total number of Ions/(Valencies of Positive and Negative Ions*Number of Positive and Negative Ions))*(([R]*Temperature)/[Faraday])*ln(Cathodic Ionic Activity/Anodic Ionic Activity). This formula also uses Universal gas constant, Faraday constant and Natural Logarithm (ln) function(s).
What are the other ways to Calculate EMF of Cell?
Here are the different ways to Calculate EMF of Cell-
  • EMF of Cell=Standard Reduction Potential of Cathode-Standard Oxidation Potential of AnodeOpenImg
  • EMF of Cell=(([R]*Temperature)/[Faraday])*(ln(Cathodic Ionic Activity/Anodic Ionic Activity))OpenImg
  • EMF of Cell=2*(([R]*Temperature)/[Faraday])*(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient)))OpenImg
Can the EMF of Concentration Cell with Transference in Terms of Valencies be negative?
Yes, the EMF of Concentration Cell with Transference in Terms of Valencies, measured in Electric Potential can be negative.
Which unit is used to measure EMF of Concentration Cell with Transference in Terms of Valencies?
EMF of Concentration Cell with Transference in Terms of Valencies is usually measured using the Volt[V] for Electric Potential. Millivolt[V], Microvolt[V], Nanovolt[V] are the few other units in which EMF of Concentration Cell with Transference in Terms of Valencies can be measured.
Copied!