Concentration of Radical in Non-Stationary Chain Reactions Formula

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Concentration of Radical given nonCR is defined as the amount of radical in the chain propagation step. Check FAQs
[R]nonCR=k1[A]-k2(α-1)[A]+(kw+kg)
[R]nonCR - Concentration of Radical given nonCR?k1 - Reaction Rate Constant for Initiation Step?[A] - Concentration of Reactant A?k2 - Reaction Rate Constant for Propagation Step?α - No. of Radicals Formed?kw - Rate Constant at Wall?kg - Rate Constant within Gaseous Phase?

Concentration of Radical in Non-Stationary Chain Reactions Example

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Here is how the Concentration of Radical in Non-Stationary Chain Reactions equation looks like with Values.

Here is how the Concentration of Radical in Non-Stationary Chain Reactions equation looks like with Units.

Here is how the Concentration of Radical in Non-Stationary Chain Reactions equation looks like.

0.0722Edit=70Edit60.5Edit-0.0001Edit(2.5Edit-1)60.5Edit+(30.75Edit+27.89Edit)
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Concentration of Radical in Non-Stationary Chain Reactions Solution

Follow our step by step solution on how to calculate Concentration of Radical in Non-Stationary Chain Reactions?

FIRST Step Consider the formula
[R]nonCR=k1[A]-k2(α-1)[A]+(kw+kg)
Next Step Substitute values of Variables
[R]nonCR=70L/(mol*s)60.5M-0.0001L/(mol*s)(2.5-1)60.5M+(30.75s⁻¹+27.89s⁻¹)
Next Step Convert Units
[R]nonCR=0.07m³/(mol*s)60500mol/m³-1.1E-7m³/(mol*s)(2.5-1)60500mol/m³+(30.75s⁻¹+27.89s⁻¹)
Next Step Prepare to Evaluate
[R]nonCR=0.0760500-1.1E-7(2.5-1)60500+(30.75+27.89)
Next Step Evaluate
[R]nonCR=72.2326238432387mol/m³
Next Step Convert to Output's Unit
[R]nonCR=0.0722326238432387M
LAST Step Rounding Answer
[R]nonCR=0.0722M

Concentration of Radical in Non-Stationary Chain Reactions Formula Elements

Variables
Concentration of Radical given nonCR
Concentration of Radical given nonCR is defined as the amount of radical in the chain propagation step.
Symbol: [R]nonCR
Measurement: Molar ConcentrationUnit: M
Note: Value can be positive or negative.
Reaction Rate Constant for Initiation Step
Reaction Rate Constant for Initiation Step is defined as the rate constant for the first reaction step in which highly reactive intermediates species like free radicals, atoms are formed.
Symbol: k1
Measurement: Second Order Reaction Rate ConstantUnit: L/(mol*s)
Note: Value should be greater than 0.
Concentration of Reactant A
Concentration of Reactant A is defined as the concentration of substance A after reacting for a given interval of time t.
Symbol: [A]
Measurement: Molar ConcentrationUnit: M
Note: Value should be greater than -1.
Reaction Rate Constant for Propagation Step
Reaction Rate Constant for Propagation Step is defined as the rate constant for the reaction step in which highly reactive intermediates reacts to produce products or new reactive intermediates.
Symbol: k2
Measurement: Second Order Reaction Rate ConstantUnit: L/(mol*s)
Note: Value should be greater than 0.
No. of Radicals Formed
No. of Radicals Formed is defined as the total number of radicals formed in the chain propagation step of a chain reaction.
Symbol: α
Measurement: NAUnit: Unitless
Note: Value should be greater than 0.
Rate Constant at Wall
Rate Constant at Wall is defined as the a coefficient of proportionality relating the rate of a chemical reaction taking place at the wall.
Symbol: kw
Measurement: First Order Reaction Rate ConstantUnit: s⁻¹
Note: Value should be greater than 0.
Rate Constant within Gaseous Phase
Rate Constant within Gaseous Phase is defined the a coefficient of proportionality relating the rate of a chemical reaction taking place within the gaseous phase.
Symbol: kg
Measurement: First Order Reaction Rate ConstantUnit: s⁻¹
Note: Value should be greater than 0.

Other formulas in Chain Reactions category

​Go Concentration of Radical formed during Chain Propagation Step given kw and kg
[R]CP=k1[A]k2(1-α)[A]+(kw+kg)
​Go Concentration of Radical formed in Chain Reaction
[R]CR=k1[A]k2(1-α)[A]+k3

How to Evaluate Concentration of Radical in Non-Stationary Chain Reactions?

Concentration of Radical in Non-Stationary Chain Reactions evaluator uses Concentration of Radical given nonCR = (Reaction Rate Constant for Initiation Step*Concentration of Reactant A)/(-Reaction Rate Constant for Propagation Step*(No. of Radicals Formed-1)*Concentration of Reactant A+(Rate Constant at Wall+Rate Constant within Gaseous Phase)) to evaluate the Concentration of Radical given nonCR, The Concentration of Radical in Non-Stationary Chain Reactions formula is defined as the amount of radical formed in a non-stationary chain reaction, i.e. when α >1. Concentration of Radical given nonCR is denoted by [R]nonCR symbol.

How to evaluate Concentration of Radical in Non-Stationary Chain Reactions using this online evaluator? To use this online evaluator for Concentration of Radical in Non-Stationary Chain Reactions, enter Reaction Rate Constant for Initiation Step (k1), Concentration of Reactant A ([A]), Reaction Rate Constant for Propagation Step (k2), No. of Radicals Formed (α), Rate Constant at Wall (kw) & Rate Constant within Gaseous Phase (kg) and hit the calculate button.

FAQs on Concentration of Radical in Non-Stationary Chain Reactions

What is the formula to find Concentration of Radical in Non-Stationary Chain Reactions?
The formula of Concentration of Radical in Non-Stationary Chain Reactions is expressed as Concentration of Radical given nonCR = (Reaction Rate Constant for Initiation Step*Concentration of Reactant A)/(-Reaction Rate Constant for Propagation Step*(No. of Radicals Formed-1)*Concentration of Reactant A+(Rate Constant at Wall+Rate Constant within Gaseous Phase)). Here is an example- 7.2E-5 = (0.07*60500)/(-1.1E-07*(2.5-1)*60500+(30.75+27.89)).
How to calculate Concentration of Radical in Non-Stationary Chain Reactions?
With Reaction Rate Constant for Initiation Step (k1), Concentration of Reactant A ([A]), Reaction Rate Constant for Propagation Step (k2), No. of Radicals Formed (α), Rate Constant at Wall (kw) & Rate Constant within Gaseous Phase (kg) we can find Concentration of Radical in Non-Stationary Chain Reactions using the formula - Concentration of Radical given nonCR = (Reaction Rate Constant for Initiation Step*Concentration of Reactant A)/(-Reaction Rate Constant for Propagation Step*(No. of Radicals Formed-1)*Concentration of Reactant A+(Rate Constant at Wall+Rate Constant within Gaseous Phase)).
Can the Concentration of Radical in Non-Stationary Chain Reactions be negative?
Yes, the Concentration of Radical in Non-Stationary Chain Reactions, measured in Molar Concentration can be negative.
Which unit is used to measure Concentration of Radical in Non-Stationary Chain Reactions?
Concentration of Radical in Non-Stationary Chain Reactions is usually measured using the Molar(M)[M] for Molar Concentration. Mole per Cubic Meter[M], Mole per Liter[M], Mole per Cubic Millimeter[M] are the few other units in which Concentration of Radical in Non-Stationary Chain Reactions can be measured.
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