The partial molar volume of a substance in a mixture is the change in volume of the mixture per mole of that substance added, at constant temperature and pressure. And is denoted by Vl. Partial Molar Volume is usually measured using the Cubic Meter per Kilomole for Molar Volume. Note that the value of Partial Molar Volume is always negative. Typically, the value of Partial Molar Volume is greater than 0.